You have a lot to learn. I'm an electrical engineer and I don't have answer to all of your questions. Some Chinese websites offer motor and controller as a kit so that solves some off your problems. But you will have to mount all this in your bike, which is different kind of engineering.
As for "watts and volts and all that". Here is the oversimplified version. 750 watts are roughly equal to one horsepower. To go 90 miles comfortably you need up to 20 hp. Batteries need to provide enough Watthours to provide power for the distance or time you want to use the bike. Watthours is Watts usage over one hour. Voltage is the pressure that pushes electrons (that is called Amperes) through the motor and causes it to rotate. Voltage and Amperes multiplied together equal Watts. You can have same Watts with either high Volts and low Amperes or low Volts and high Amperes. High Amperes need thick heavy wires, high voltage needs bulky insulation (and is more likely to kill you if you touch the wires). Look at electric bike as chemical, to electric, to kinetic, energy conversion and remember that no conversion is 100% efficient.
My advice is, be careful and start by buying an fire extinguisher.