First of all, good luck with the project!
I avoid calling myself an expert as there is always someone with better knowledge that you
anyway, these are my 5 cents:
There is a bunch of information over the Internet about this subject.
When building a battery pack there are a few main considerations, one is topology (the way they are connected serial, parallel, etc...), welding (cells get severely damaged if this process is not done properly and the process itself is also dangerous), and chemistry (you need to chose the right one, my advice is to got for LiFe, or better yet Lithium manganese. These chemistries are pretty safe within the challenges Lithium represents in the "safety world" and last, but not least charging and Battery management.
- Pouch cells are better than cylindrical because of space, but you may be able to find better deals in cylindrical ones
- Make sure you do not mix cell chemistries...nominal voltages are not the same
- When preforming the sensitive welding process use proper plates (avoid wiring) solid copper or nickel. A spot welding might not be a bad choice
- Make sure you reach a level on consistency in cell "health" or capacity, whatever you call it, when connecting/soldering them. Inconsistency in this will build a messy and unreliable pack
- Got a precision multimeter and a high Amp clamp already?
- Get a charger and a BMS suitable for the voltage you will be dealing with. They are relatively cheap
- Get proper fuses in main High current connections, and be careful with ground connections
- Get a proper quality aluminium case. If the pack is big, it has to be strong enough...Obvious?
- Get a way of measuring pack temp to avoid cells typical de-charging high temperature (lithium loves working in relatively "warm weather" but also hates being charged when hot after use)
- Be careful if you plan in going for a high voltage pack. These are not toys and you could either get severally injured or die...DC voltage in opposite with AC one gives little opportunity to release your hand if you ever touch a cable