I read somewhere that one can't expect perfectly balanced cells at both top and bottom end of the SoC. And that cells can be perfectly balanced at a particular SoC, but will become disbalanced at other SoC. They can br rebalanced at that new SoC, but that will cause them to be disbalanced at other SoC-es. The reason is that cells in the pack have slightly different capacities and internal resistances and sometimes temperatures from each other. Resulting in slightly different charge/discharge curves for the different cells. On top of that, you got the BMS that introduces disbalances by monitoring the cells and drawing unevenly from each cell. The result is that, suppose you start with top-balanced cells, as they discharge, they end-up slightly disbalanced. At that point, the BMS hopefully detects this condition and tries to protect the weakest (emptiest) cells, even though the overall SoC of the pack may indeed be way above "empty". So it cuts power.
On my Vectrix with Nissan Leaf cells, I do not have a BMS. My cells are top-balanced to within a few 1/1000 of a Volt. But as I drain the battery, towards the lower SoC, they get differences as big as 1/10 of a Volt, a 100 times more than where they started when fully charged. However, since they were all drained by the same amount, as I charge them back and as their SoC reaches back towards "fully" charged (somewhere 10-20% below max. rated capacity actually is where my "full charge" is), they again become almost perfectly balanced. Over about 2,000 miles, charging every 40-60 miles, they still remain top-balanced. The lack of BMS (and the good quality of the Nissan cells) really helps keep the cells top-balanced.
The better BMS systems actively balance cells when in use, not just during charging. Does anyone know what type the BMS in the Zero is? I.e., does it just top-balance during charging or does it also actively balance while riding?
Cell imbalance, low temp ( make voltage sag) have huge effect also on the last % SOC.
On my modified 2012 S ZF15 i have 13400Wh usable ( 200Ah at 66V) and i can get all the 13400Wh and reach 2%soc no prob everytime. The cells are perfectly balanced.
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