That sprocket looks really nice! I've had good results using HD 428 chain on my ICE bikes, it's light and low-drag.
The FX chain kit (520) has 12T front / 65T rear sprockets, for a 5.42:1 ratio (about 2.6% lower than 25/132). I think they may have done this to minimize changes in RW torque and speedo readings when using knobbies, which are generally larger in diameter than the OEM low-profile IRC.
I've been looking at all-steel-wear-points chain options to get the front wheel up easier on my FX, and it seems the easiest route might be 530 chain, which has the same dimensions as ANSI #50. Martin makes 1"-shaft 1" wide #50 front sprockets from 10T to 23T, and I believe both SuperSprox and Sidewinder make custom 530 hybrid rear sprockets up to 70T (I'm waiting to hear back from both).
The '04-'15 KTM 85SX rear wheel appears to use an identical sprocket mounting setup to my FX (four M8 holes in 132mm dia. circle, 110mm center hole) which made spec'ing the custom sprockets a lot easier.
Ray