Current splitting between the two batteries will depend upon their internal resistance. The cables, or wires, from the DiamondPower battery look pretty thin.. so maybe you are lucky and it has high resistance.
If you crack open the throttle on the XU at 30-40 mph it will probably pull 200 amps from the combined battery. I believe you can tune the controller to limit maximum current, in case the current split would exceed the 75 amp limit on the secondary battery.
I assume you will charge the batteries separately. How will you ensure they are charged to a level voltage before connecting?
XU battery is 14s ~3.0v to 4.2v. Not sure about lower limit. So total voltage range 42v to 58.8v. This is 2.8v to 3.92v for your lifepo4 cells.
This is the battery pack?
http://www.ebay.com/itm/48V30Ah-1500W-E-Bike-E-Bicycle-scooter-Waterproof-LiFePO4-Battery-and-Charger-/121176666496?pt=Cycling_Parts_Accessories&hash=item1c36b13180Picture 4
Professional Waterproof and Dustproof connectors
Connect the battery to your ebike controller or your device
Max rated current: 52A (6mm2, AWG10)
Conventional rated current: 30A
Looks like the cells are limited to max 2C discharge (60A), BMS is limited to 60A cont 75A max, connectors are limited to 30A cont 52A max. I would recommend at least replacing the connectors to ensure they do not overheat.