higher voltage is more efficient, you can use smaller cables, and you can produce more HP with that Etek.
voltage equates to RPM.
Current equates to torque.
Higher Voltage controller, Higher RPM. Higher RPM, and you might get more HP out of the motor.
Higher current controller, higher torque. Higher torque also gets you higher HP.
SLA and Lifepo4 don't really matter for controllers that are programmable (Like the Alltrax AXE controllers, Kelly controllers, Sevcon). If its like some of the other Alltrax, or one of the curtis controllers, you may have trouble, I don't know, you'll need to research that.
Lead is cheap and easy but you might not get the range you want for the weight. Lifepo4 is more expensive but allows you to lighten things up a bit and thus get more range for the same amount of energy.