So first of all, it doesn't need to be that specific unit. I just googled up an example battery pack that has separate input and output at 12v. DC-DC is great, but you'd need to tap into 100v output from the pack bypassing contactor and basically without internal BMS. I think you understand where this is going... So you have two choices then - treat it like a portable power pack, charging it separately whenever needed, or wire its power supply onto the pins of C13 port in parallel with onboard charger.
Now I may have heard something about constant output somewhere on the BMS. If I am remembering correctly, perhaps it can be utilized if not to drive the actual load (even if via step-up DC-DC if it's only 5v), or at least controlling some relay when tapping into 100v while retaining pack management. But that is seriously more complicated than the two options above.